By S. J. Gregg
The imperative objective of the second one version of this ebook is still just like that of the 1st version: to provide a severe exposition of using the adsorption equipment for the overview of the outside and pore measurement distribution of finely divided and porous solids.
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Additional info for Adsorption, Surface Area, & Porosity, Second Edition
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Hence, the extension of p-QDM can generate another interesting π-scaﬀold with signiﬁcant diradical character. Electron-withdrawing cyano (CN) groups, at the terminal methylene sites (radical centers), are also usually employed to gain better stability for the extended p-QDM derivatives . 17), which should favor a closed-shell ground state (91-C and 93-C), as two aromatic Clar’s sextets are lost in their respective diradical resonance forms . However, the closed-shell forms of 91 and 93 adopt a contorted geometry with a larger steric hindrance among the anthryl peri hydrogens, making the corresponding orthogonal diradical structures (91-O and 93-O) more favorable.
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Adsorption, Surface Area, & Porosity, Second Edition by S. J. Gregg