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By C.H. Bamford

ISBN-10: 0444410511

ISBN-13: 9780444410511

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Extra info for Addition and Elimination Reactions of Aliphatic Compounds

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In this situation, it seems possible that molecules of hydrogen bromide are acting as solvent molecules. However, other interpretations include a termolecular collision process, involving a transition state such as I (ref. 5) which are thought to be more acidic speciesfio. 5) SIDE REACTIONS The addition of acids to olefins, since it involves the formation of a carbonium ionic species, will be subject to a number of side reactions which divert the course of the reaction by providing other routes through which the carbonium ion may be attacked.

8 x 10-5 2,4-Mg-l-pentene k, = 1 . 42 x 10-4 X = 1 2 . 61 x = 2 . 4 25 35 45 115 130 Me0 MeOH MeOH MeOH MeOH MeOH MeOH MeOH MeOH C: SO,H C7H7S0,H C,H,SO,H C,H7S03H C7H7S0,H C,H,SO,H C,H7S0,H C7H,S0,H C,H7SO,H H,SO,aq. H,SO,aq. H,S04aq. H,SO,aq. H,SO,aq. H,S04aq. 66 X a 30 30 30 30 30 30 For truns addition of DBr. For cis addition of DBr. Derived from quoted rate coefficients. From the parameters in Table 111, ref. 99h,1-1R at 25°C. -d [CzH4]/dt = k,[C,H,] +constant. k , does not vary linearly with any acidity function; see however, refs.

The addition of hydrogen bromide to olefins is a good example. In this situation, it seems possible that molecules of hydrogen bromide are acting as solvent molecules. However, other interpretations include a termolecular collision process, involving a transition state such as I (ref. 5) which are thought to be more acidic speciesfio. 5) SIDE REACTIONS The addition of acids to olefins, since it involves the formation of a carbonium ionic species, will be subject to a number of side reactions which divert the course of the reaction by providing other routes through which the carbonium ion may be attacked.

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Addition and Elimination Reactions of Aliphatic Compounds by C.H. Bamford


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